Soil type affects migration pattern of airborne Pb and Cd under a spruce-beech forest of the UN-ECE integrated monitoring site Zöbelboden, Austria

Anthropogenic trace element emissions have declined. However, top soils all over the world remain enriched in trace elements. We investigated Pb and Cd migration in forest soils of a remote monitoring site in the Austrian limestone Alps between 1992 and 2004. Large spatial variability masked temporal changes in the mineral soil of Lithic Leptosols (Skeltic), whereas a significant reduction of Pb concentrations in their forest floors occurred. Reductions of concentrations in the less heterogeneous Cambisols (Chromic) were significant. In contrast, virtually no migration of Pb and Cd were found in Stagnosols due to their impeded drainage. Very low element concentrations (<1 μg l⁻¹) in field-collected soil solutions using tension lysimeters (0.2 μm nylon filters) imply that migration largely occurred by preferential flow as particulate-bound species during intensive rainfall events. Our results indicate that the extent of Pb and Cd migration in soils is largely influenced by soil type.     

改性膨润土作为垃圾渗透液防渗层的实验研究

本文以天然钠基膨润土为原料，采用水溶液聚合法，在室温条件下，通过改性聚丙烯酰胺对膨润土进行直接插层改性，制备了一种新型聚丙烯酰胺改性膨润土防渗材料。以此防渗材料作为防渗层，选用沈阳大辛填埋场的垃圾渗透液为处理对象，在动态实验下，就其对实际垃圾渗滤液中主要污染物去除的有效性和控制垃圾渗滤液渗透的可行性进行研究。抗渗性能测试结果表明，改性膨润土防渗性能较好，渗透系数为1．0×10^-7cm/s，达到固体废物填埋场的防渗材料国家标准1．0×10^-7cm／s的使用要求。改性膨润土防渗层对COD、氨氮、重金属离子去除效果较好，吸附作用较强，COD和氨氮最大去除率分别达到81％和91％，TFe、Zn^2＋和TCr的最大去除率分别达到71％、58％和73％。实验结果验证了本研究所制备的改性膨润土防渗材料具有优良的抗渗、截污性能。     

基于正交试验响应面法的烟气层概率分布计算

为计算随机参数下火灾烟气层温度和厚度的概率分布，该文提出了基于正交试验响应面的可靠度计算方法。通过正交试验表确定分析计算参数组，并借助火灾动力学分析软件计算不同参数组下烟气层的温度和厚度响应，进一步拟合出输入参数和输出参数的响应面函数，在此基础上结合验算点法计算烟气层温度和厚度的概率分布，算例分析表明该方法具有计算精度高、计算量小的特点。     

粉状活性焦在双层滤料颗粒床中的脱硫试验研究

在双层滤料颗粒床模型试验台上对粒径为300～400目的粉状活性焦进行了脱硫试验,研究了温度、O2和水蒸气体积分数、气体流速、再生次数对脱硫效果的影响.试验结果表明.温度为120℃、O2体积分数为8%、水蒸气体积分数为10%条件下,脱硫效果最好;粉状活性焦在双层滤料颗粒床中经过7次重复吸附.达到硫饱和吸附量为66.2 mg/g.粉状活性焦再生试验表明,随着再生次数的增加.粉状活性焦的脱硫性能呈下降趋势.     

Potential and Shortcomings of Numerical Weather Prediction Models in Providing Meteorological Data for Urban Air Pollution Forecasting

The last decade progress in numericalweather prediction (NWP) modelling and studies of urbanatmospheric processes for providing meteorological data forurban air pollution forecasting is analysed on examples ofseveral European meteorological centres. Modern nested NWP models are utilising land-use databasesdown to 1 km resolution or finer, and are approaching thenecessary horizontal and vertical resolution suitable forcity scale. The recent scientific developments in the fieldof urban atmospheric physics and the growing availabilityof high-resolution urban surface characteristics datapromise further improvements of the capability of NWPmodels for this aim. A strategy to improve NWP data forthe urban air pollution forecasting is suggested.     

煤体注水湿润半径预测的神经网络模型

合理的注水半径一直是煤体注水防尘技术中难以确定的参数。笔者基于对影响煤体注水半径因素的分析和神经网络理论的原理之上 ,设计网络模型为 3层 ,输入层为 7个节点 ,应用BP网络算法 ,建立了煤体注水湿润半径的预测模型 ,并对其参数进行了讨论。然后 ,用平顶山矿务局和水城矿务局 13个矿 19个回采工作面的统计资料对BP网络进行自适应学习 ,并取η =0 .9,α =0 .82 ,控制网络总误差E≤ 10 6。经过 2 12 34次迭代后 ,网络趋于稳定。用训练好的网络对平顶山矿务局的某矿的 3层煤的注水湿润半径进行预测 ,预测结果与实测值很接近。其误差分别为 0 .5 %,0 .6 %和 0 .7%。     

带防腐层在役压力容器表面磁粉探伤灵敏度的试验研究

采用人工裂纹试样的方法 ,模拟压力容器涂刷油漆防腐层的状况进行磁粉探伤 ,得出了油漆防腐层厚度与裂纹检出灵敏度的定量关系 ;结合CVDA《压力容器缺陷评定》规范 ,探讨了试验方法对一般在役压力容器带有油漆的情况下 ,进行磁粉探伤检验的可行性。研究表明 :采用交流磁化法进行探伤 ,当漆层厚度大约小于2 5 0 μm时 ,灵敏度影响较小 ,同时亦表明不宜使用直流磁化方法。该结论对承受低应力工况条件下的压力容器安全质量检验和评估 ,具有重要参考价值     

最大剪切模量对土动力参数及地震反应的影响

最大剪切模量是影响土的动剪切模量比、阻尼比和土层地震反应的最重要参数之一。通常采用室内应变法来确定最大剪切模量，给出土的动剪切模量比和阻尼比，而采用现场剪切波速法求得的结果则很少见。研究了剪切波速法和应变法所确定的最大剪切模量对土动剪切模量比、阻尼比和土层地震反应的影响，推导了两种方法所确定的动剪切模量比和阻尼比之间的关系式。结果表明：最大动剪切模量对土的动剪切模量比、阻尼比和土层地震反应的影响很显著。     

Influence of the oxide content on the ignition energies of aluminium powders

Some results of determination of ignition energies for an aluminium powder with various oxide contents are presented. Common use of processes like high-speed cutting produce explosive dust clouds, so that we focused this study on hazard of metallic powders. An industrial aluminium powder has been used for this work. An original process, based on the principle of electrochemical anodisation, has been developed to increase, under control, the oxide coating of particles.

The sensitivity study to spark ignition was performed in an Hartmann explosion tube of 1.3L. The Langlie test method was applied to evaluate the energies leading to a probability of ignition of 50% (E₅₀) of the selected samples. The results confirm that the ignition energies increase with the oxide content of the powder.     

川西气田地层水回注选井选层研究

根据川西气田的实际情况,对致密砂岩层回注选井选层技术进行研究,初步建立了致密砂岩层回注选井选层技术,优选出川西气田1、2、3号等5个回注井区。目前,注水规模300m3/d,累计注水量达75 698.8m3,节约生产成本约200万元,且有效缓解了高浓度氯离子地层水外排带来的环保压力。现场回注试验表明:致密砂岩层回注高浓度氯离子地层水是可行的,回注选井选层技术具有现场推广应用价值。